Angelina Jolie"s only movie in 2005 was the action-comedy Mr. & Mrs. Smith.

Action-comedy Mr. & Mrs. Smith film, directed by Doug Liman, tells the story of a bored married couple who find out that they are both secret assassins. Angelina Jolie starred as Jane Smith alongside Brad Pitt.

Action-comedy Mr. & Mrs. Smith film was well received and was generally lauded for the chemistry between the two leads Angelina Jolie and Brad Pit. The Star Tribune noted, "While the story feels haphazard, the movie gets by on gregarious charm, galloping energy and the stars" thermonuclear screen chemistry."

Action-comedy Mr. & Mrs. Smith movie earned $478 million worldwide, one of the biggest hits of 2005.